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二维纳米片/聚合物高阻隔复合材料研究进展
葛畅1,田潇2,程有亮2,方长青2,巩佳豪1,杨芳1,王海英1,曹稳1,赵晓梅1
1.陕西中烟工业有限责任公司,西安 710065;2.西安理工大学,西安 710048
摘要:
目的 通过综述二维纳米片/聚合物高阻隔复合材料的制备方法和性能,为高阻隔二维纳米片/聚合物复合材料的制备提供可靠依据和文献支撑。方法 基于不同二维纳米材料的改性方法及应用场景,总结二维纳米材料与聚合物的复合方法,比较分析其阻隔效果,进而寻找符合应用要求的高阻隔二维纳米片/聚合物复合材料。结果 二维纳米材料的种类不同,其物理特性和改性方法也不同;二维纳米片和聚合物的复合方法有很多种,形成的复合材料在阻隔性能和阻隔机制方面也存在较大差异。结论 二维纳米材料/聚合物复合材料的阻隔性能由多个方面决定,包括二维纳米材料的形态和结构、分散特性及与聚合物基体的相容性等,这为高阻隔二维纳米片/聚合物复合材料的设计提供了思路和指导方法。
关键词:  蒙脱土  氮化硼  氧化石墨烯纳米片  插层复合法  共混法  溶胶凝胶法
DOI:10.19554/j.cnki.1001-3563.2025.07.005
分类号:
基金项目:陕西中烟工业有限责任公司委托项目(2023610000340444)
Research Progress on Two-dimensional Nanosheets/Polymer High Barrier Composites
GE Chang1, TIAN Xiao2, CHENG Youliang2, FANG Changqing2, GONG Jiahao1, YANG Fang1, WANG Haiying1, CAO Wen1, ZHAO Xiaomei1
(1.China Tobacco Shaanxi Industrial Co., Ltd., Xi'an 710065, China;2. Xi'an University of Technology, Xi'an 710048, China)
Abstract:
The work aims to review the preparation methods and properties of two-dimensional nanosheet/polymer composites with high barrier properties to provide a reliable basis and literature support for the preparation of such composites. Based on the modification methods and application scenarios of different two-dimensional nanomaterials, the composite methods of two-dimensional nanomaterials and polymers were summarized, and their barrier effects were compared and analyzed to find high-barrier two-dimensional nanosheet/polymer composites that met application requirements. Different types of two-dimensional nanomaterials had different physical properties and modification methods. There were also various composite methods for two-dimensional nanosheets and polymers. The formed composites had significant differences in barrier properties and barrier mechanisms. In conclusion, the barrier properties of two-dimensional nanomaterial/polymer composites are determined by multiple aspects, including the morphology and structure of two-dimensional nanomaterials, dispersion characteristics, and compatibility with the polymer matrix. This provides ideas and guiding methods for the design of polymer composites with high barrier properties.
Key words:  montmorillonite  boron nitride  graphene oxide nanosheets  intercalation method  blending method  sol-gel method

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