| 摘要: |
| 目的 对国内外MOF/聚合物复合膜的基底种类进行综述，并总结聚合物基底的表面改性或修饰方法的研究进展，从而在一定程度上丰富MOF/聚合物复合膜的种类。方法 总结和分析MOF/聚合物复合膜的基底，即选择聚酯、聚酰胺、聚乙烯醇、聚苯乙烯和聚砜等聚合物材料作为基底的最新研究成果；对聚合物基底的表面改性或修饰方法及主要机理进行阐述；展望MOF/聚合物复合膜的应用前景。结果 MOF/聚合物复合膜的基底种类以及基底表面的改性或修饰方法虽呈现多样化趋势，但MOF/聚合物复合膜制备的简便性、普遍性还有待进一步提高。结论 总结了现有MOF/聚合物复合膜的基底种类，并分析了其表面改性或修饰方法，为进一步开发MOF/聚合物复合膜的应用潜能打下了良好基础。 |
| 关键词: MOF晶体薄膜 金属有机框架材料 基底 表面改性 |
| DOI：10.19554/j.cnki.1001-3563.2020.03.021 |
| 分类号:TB333；TB43 |
| 基金项目: |
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| Research Progress of MOF/Polymer Composite Film Substrates |
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ZHANG Ning, XIAO Feng, CAO Yuan-qing, ZHAO Hui
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College of Light Industry Science and Engineering, Tianjin University of Science & Technology, Tianjin 300222, China
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| Abstract: |
| The work aims to review the substrate types of MOF/polymer composite films at home and abroad, and summarize the research progress of surface modification or embellishment method of polymer substrates, so as to enrich the types of MOF/polymer composite films to a certain extent. The substrates of MOF/polymer composite films were summarized and analyzed, that is, the latest research results were obtained by selecting polyester, polyamide, polyvinyl alcohol, polystyrene and polysulfone as substrates. The methods of surface modification or embellishment of polymer substrates and their main mechanisms were described. The application of MOF/polymer composite films was also prospected. The substrate types of MOF/polymer composite films, and the modification or embellishment method of the substrate surface showed a trend of diversification, but the simplicity and universality of the preparation of MOF/polymer composite films needed to be further improved. After summarizing the existing substrate types of MOF/polymer composite films and analyzing their surface modification or embellishment method, a good foundation has been laid for further developing the application potential of MOF/polymer composite films. |
| Key words: MOF crystal film metal-organic frameworks substrate surface modification |
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