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染料与纤维共磨对纸浆模塑染色和强度性能的影响
刘旭, 张志礼, 杨仁党
华南理工大学 制浆造纸工程国家重点实验室,广州 510640
摘要:
目的 探究深色纸浆模塑制品染色过程中出现色差的机理,研究染料与纤维共磨对染色效果和强度性能的影响,提出改善深色纸浆模塑制品染色效果与强度性能的工艺。方法 在相同磨浆转数下,探究染料的加入方式对纤维形态、染色制品强度、光学性能及染料上染率的影响;将染料与纤维共磨,探究不同磨浆转数对浆料的滤水性能、染色制品的染色效果和强度的影响。结果 实验证实,染料和纤维共磨有利于改善染色制品的抗张强度和耐破强度,能在显著提高染色效果的同时有效降低染色制品的正反面色差。与传统添加方式相比,染色制品的色差由2.53缩小到0.20,上染率从72.02%提高到了77.93%。显微镜图像分析显示,共磨浆料的纤维起毛现象更明显。此外,随着磨浆转数增加,染色制品的光学性能和强度性能得到提高。结论 染料与纤维共磨可以提高打浆效果,改善深色纸浆模塑制品的染色效果和强度性能。
关键词:  染料  纸浆模塑  共磨  染色效果  强度  上染率
DOI:10.19554/j.cnki.1001-3563.2018.09.010
分类号:TS753.9
基金项目:国家重点研发计划(2017YFB0307900)
Effect of Co-refining of Dyes and Fibers on the Dyeing Performance and Strength of Pulp Molded Products
LIU Xu, ZHANG Zhi-li, YANG Ren-dang
State Key Laboratory of Pulp & Paper Engineering, South China University of Technology, Guangzhou 510640, China
Abstract:
The work aims to study the mechanism of color difference in dyeing process of dark pulp molded product and the effect of co-refining of dyes and fibers on dyeing performance and strength, and propose the technology to improve the dyeing performance and strength of dark pulp molded products. Under the same number of revolutions, the effects of adding methods of dyes on fiber morphology, and strength, optical performance and dye uptake rate of dyed products were investigated. The dyes and fibers were co-refined to discuss the effects of different refining revolutions on the drainage properties of pulp and the dyeing performance and strength of dyed products. The experiment proved that co-refining of the dyes and fibers was conducive to improving the tensile strength and bursting strength of the dyed products, significantly improving the dyeing effects and effectively reducing the color difference of both sides of the dyed products. Compared with the traditional adding methods, the color difference of dyed products reduced from 2.53 to 0.20, and the dye uptake rate increased from 72.02% to 77.93%. Microscope image analysis showed that the fiber picks were more remarkable in the co-refined slurry. In addition, with the increase of refining revolutions, the optical performance and strength of dyed products were improved. Co-refining of dyes and fibers can enhance the beating effect and improve the dyeing performance and strength of dark pulp molded product.
Key words:  dye  pulp molded products  co-refining  dyeing performance  strength  dye uptake rate

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