摘要: |
采用流延成膜工艺制备了CCMC/PVA共混复合膜,研究了戊二醛交联剂对复合膜的透光性能和力学性能的影响。结果表明:交联处理膜的致密性和机械性能显著提高;当戊二醛添加量为2%(质量分数),体系的pH为10,交联反应温度为85 ℃,交联时间为35 min时,复合膜的拉伸强度可达18.91 MPa,断裂伸长率为226%,透光率为75%。 |
关键词: 戊二醛 交联羧甲基纤维素 复合膜 特性 |
DOI: |
分类号:TB484.3; TB332 |
基金项目:国家星火计划(2008GA670021) |
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Effect of Glutaraldehyde Crosslinking on Performance of CCMC/PVA Blend Films |
LU Bao-xin1, WANG Xi-gang2, ZHOU Rui1, CAO Long-kui3,4
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1.Heilongjiang Bayi Agricultural University, Daqing 163319, China;2.Jiusan Group Tianjin Soya Science and Technology Co., Ltd., Tianjin 300461, China;3.1.Heilongjiang Bayi Agricultural University, Daqing 163319, China;4.2.Heilongjiang Farm Produce Processing Development Centre, Daqing 163319, China
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Abstract: |
CCMC/PVA blend film was prepared by solution mixing method. The effect of glutaric dialdehyde crosslinking agent on the hydrolytic resistance, light transmission and mechanical property of CCMC/ PVA complex film were studied. The results showed that the compactness, water resisting property and mechanical property of CCMC/PVA blend film increased remarkably by crosslinking treatment. The tensile strength was 18.91 MPa, elongation at break was 226%, luminousness was 75% when the amount of glutaric dialdehyde was 2%, pH was 10, crosslinking reaction temperature was 85 ℃, and reaction time was 35 min respectively. |
Key words: glutaric dialdehyde cross-linked carboxymethyl cellulose complex film property |